In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which an atomic nucleus emits a beta particle (fast energetic electron or positron), transforming into an isobar of that nuclide. For example, beta decay of a neutron transforms it into a proton by the emission of an electron accompanied by an antineutrino; or, conversely a proton is converted into a neutron by the emission of a positron with a neutrino in what is called positron emission. Neither the beta particle nor its associated (anti-)neutrino exist within the nucleus prior to beta decay, but are created in the decay process. By this process, unstable atoms obtain a more stable ratio of protons to neutrons. The probability of a nuclide decaying due to beta and other forms of decay is determined by its nuclear binding energy. The binding energies of all existing nuclides form what is called the nuclear band or valley of stability. For either electron or positron emission to be energetically possible, the energy release (see below) or Q value must be positive.
Beta decay is a consequence of the Weak interaction, which is characterized by relatively long decay times. Nucleons are composed of and , and the weak force allows a quark to change its flavour by means of a virtual W boson leading to creation of an electron/antineutrino or positron/neutrino pair. For example, a neutron, composed of two down quarks and an up quark, decays to a proton composed of a down quark and two up quarks.
Electron capture is sometimes included as a type of beta decay, because the basic nuclear process, mediated by the weak force, is the same. In electron capture, an inner atomic electron is captured by a proton in the nucleus, transforming it into a neutron, and an electron neutrino is released.
Beta decay conserves a quantum number known as the lepton number, or the number of electrons and their associated neutrinos (other leptons are the muon and tau particles). These particles have lepton number +1, while their antiparticles have lepton number −1. Since a proton or neutron has lepton number zero, β+ decay (a positron, or antielectron) must be accompanied with an electron neutrino, while β− decay (an electron) must be accompanied by an electron antineutrino.
An example of electron emission (β− decay) is the decay of carbon-14 into nitrogen-14 with a half-life of about 5,700 years:
In this form of decay, the original element becomes a new chemical element in a process known as nuclear transmutation. This new element has an unchanged mass number , but an atomic number that is increased by one. As in all nuclear decays, the decaying element (in this case ) is known as the parent nuclide while the resulting element (in this case ) is known as the daughter nuclide.
Another example is the decay of hydrogen-3 (tritium) into helium-3 with a half-life of about 12.3 years:
An example of positron emission (β+ decay) is the decay of magnesium-23 into sodium-23 with a half-life of about 11.3 s:
The beta spectrum, or distribution of energy values for the beta particles, is continuous. The total energy of the decay process is divided between the electron, the antineutrino, and the recoiling nuclide. In the figure to the right, an example of an electron with 0.40 MeV energy from the beta decay of 210Bi is shown. In this example, the total decay energy is 1.16 MeV, so the antineutrino has the remaining energy: . An electron at the far right of the curve would have the maximum possible kinetic energy, leaving the energy of the neutrino to be only its small rest mass.
In 1900, Becquerel measured the mass-to-charge ratio () for beta particles by the method of J.J. Thomson used to study cathode rays and identify the electron. He found that for a beta particle is the same as for Thomson's electron, and therefore suggested that the beta particle is in fact an electron.
In 1901, Rutherford and Frederick Soddy showed that alpha and beta radioactivity involves the transmutation of atoms into atoms of other chemical elements. In 1913, after the products of more radioactive decays were known, Soddy and Kazimierz Fajans independently proposed their radioactive displacement law, which states that beta (i.e., ) emission from one element produces another element one place to the right in the periodic table, while alpha emission produces an element two places to the left.
A second problem is related to the conservation of angular momentum. Molecular band spectra showed that the nuclear spin of nitrogen-14 is 1 (i.e., equal to the reduced Planck constant) and more generally that the spin is integral for nuclei of even mass number and half-integral for nuclei of odd mass number. This was later explained by the proton-neutron model of the nucleus. Beta decay leaves the mass number unchanged, so the change of nuclear spin must be an integer. However, the electron spin is 1/2, hence angular momentum would not be conserved if beta decay were simply electron emission.
From 1920 to 1927, Charles Drummond Ellis (along with Chadwick and colleagues) further established that the beta decay spectrum is continuous. In 1933, Ellis and Nevill Mott obtained strong evidence that the beta spectrum has an effective upper bound in energy. Niels Bohr had suggested that the beta spectrum could be explained if conservation of energy was true only in a statistical sense, thus this principle might be violated in any given decay. However, the upper bound in beta energies determined by Ellis and Mott ruled out that notion. Now, the problem of how to account for the variability of energy in known beta decay products, as well as for conservation of momentum and angular momentum in the process, became acute.
In a famous letter written in 1930, Wolfgang Pauli attempted to resolve the beta-particle energy conundrum by suggesting that, in addition to electrons and protons, atomic nuclei also contained an extremely light neutral particle, which he called the neutron. He suggested that this "neutron" was also emitted during beta decay (thus accounting for the known missing energy, momentum, and angular momentum), but it had simply not yet been observed. In 1931, Enrico Fermi renamed Pauli's "neutron" the "neutrino" ('little neutral one' in Italian). In 1933, Fermi published his landmark theory for beta decay, where he applied the principles of quantum mechanics to matter particles, supposing that they can be created and annihilated, just as the light quanta in atomic transitions. Thus, according to Fermi, neutrinos are created in the beta-decay process, rather than contained in the nucleus; the same happens to electrons. The neutrino interaction with matter was so weak that detecting it proved a severe experimental challenge. Further indirect evidence of the existence of the neutrino was obtained by observing the recoil of nuclei that emitted such a particle after absorbing an electron. Neutrinos were finally detected directly in 1956 by the American physicists Clyde Cowan and Frederick Reines in the Cowan–Reines neutrino experiment.
The properties of neutrinos were (with a few minor modifications) as predicted by Pauli and Fermi.
The theory of electron capture was first discussed by Gian-Carlo Wick in a 1934 paper, and then developed by Hideki Yukawa and others. K-electron capture was first observed in 1937 by Luis Alvarez, in the nuclide 48V.
Alvarez went on to study electron capture in 67Ga and other nuclides.
Another example is when the free neutron () decays by decay into a proton ():
At the fundamental level (as depicted in the Feynman diagram on the right), this is caused by the conversion of the negatively charged () down quark to the positively charged () up quark, which is promoted by a virtual W boson; the boson subsequently decays into an electron and an electron antineutrino:
However, decay cannot occur in an isolated proton because it requires energy, due to the mass of the neutron being greater than the mass of the proton. decay can only happen inside nuclei when the daughter nucleus has a greater binding energy (and therefore a lower total energy) than the mother nucleus. The difference between these energies goes into the reaction of converting a proton into a neutron, a positron, and a neutrino and into the kinetic energy of these particles. This process is opposite to negative beta decay, in that the weak interaction converts a proton into a neutron by converting an up quark into a down quark resulting in the emission of a or the absorption of a . When a boson is emitted, it decays into a positron and an electron neutrino:
An example of electron capture is one of the decay modes of krypton-81 into bromine-81:
All emitted neutrinos are of the same energy. In proton-rich nuclei where the energy difference between the initial and final states is less than 2, decay is not energetically possible, and electron capture is the sole decay mode.
If the captured electron comes from the innermost shell of the atom, the Electron shell, which has the highest probability to interact with the nucleus, the process is called K-capture.
If it comes from the L-shell, the process is called L-capture, etc.
Electron capture is a competing (simultaneous) decay process for all nuclei that can undergo β+ decay. The converse, however, is not true: electron capture is the only type of decay that is allowed in proton-rich nuclides that do not have sufficient energy to emit a positron and neutrino.
Beta decay does not change the number () of in the nucleus, but changes only its electric charge . Thus the set of all with the same can be introduced; these isobaric nuclides may turn into each other via beta decay. For a given there is one that is most stable. It is said to be beta stable, because it presents a local minimum of the mass excess: if such a nucleus has numbers, the neighbour nuclei and have higher mass excess and can beta decay into , but not vice versa. For all odd mass numbers , there is only one known beta-stable isobar. For even , there are up to three different beta-stable isobars experimentally known; for example, , , and are all beta-stable. There are about 350 known beta-decay stable nuclides.
Three types of beta decay in competition are illustrated by the single isotope (29 protons, 35 neutrons), which has a half-life of about 12.7 hours. Atomic and Nuclear Data: Chapter 12 Cu-64 Laboratoire National Henri Becquerel, 2011. Retrieved on 2024-05-01. This isotope has one unpaired proton and one unpaired neutron, so either the proton or the neutron can decay. This particular nuclide is almost equally likely to undergo proton decay (by positron emission, 18% or by electron capture, 43%; both forming ) or neutron decay (by electron emission, 39%; forming ).
Beta decay just changes neutron to proton or, in the case of positive beta decay (electron capture) proton to neutron so the number of individual quarks doesn't change. It is only the baryon flavor that changes, here labelled as the isospin.
Up and down quarks have total isospin and isospin projections
All other quarks have .
In general
The electron and antineutrino are fermions, spin-1/2 objects, therefore they may couple to total (parallel) or (anti-parallel).
For forbidden decays, orbital angular momentum must also be taken into consideration.
Since the rest mass of the electron is 511 keV, the most energetic beta particles are ultrarelativistic, with speeds very close to the speed of light.
In the case of Re, the maximum speed of the beta particle is only 9.8% of the speed of light.
The following table gives some examples:
Because the reaction will proceed only when the value is positive, β− decay can occur when the mass of atom is greater than the mass of atom .
Because the reaction will proceed only when the value is positive, β+ decay can occur when the mass of atom exceeds that of by at least twice the mass of the electron.
Because the binding energy of the electron is much less than the mass of the electron, nuclei that can undergo β+ decay can always also undergo electron capture, but the reverse is not true.
As an example, the beta decay spectrum of 210Bi (originally called RaE) is shown to the right.
For non-relativistic betas (), this expression can be approximated by:
Other approximations can be found in the literature.
The higher the energy of the particles, the higher their polarization.
Other decay modes, which are rare, are known as bound state decay and double beta decay.
For fully ionized atoms (bare nuclei), it is possible in likewise manner for electrons to fail to escape the atom, and to be emitted from the nucleus into low-lying atomic bound states (orbitals). This cannot occur for neutral atoms with low-lying bound states which are already filled by electrons.
Bound-state β decays were predicted by Raymond Daudel, Jean, and Lecoin in 1947, and the phenomenon in fully ionized atoms was first observed for Dy in 1992 by Jung et al. of the Darmstadt Heavy-Ion Research Center. Though neutral Dy is stable, fully ionized Dy undergoes β decay into the K and L shells with a half-life of 47 days.
The resulting nucleus – Ho – is stable only in this almost fully ionized state and will decay via electron capture into Dy in the neutral state. Likewise, while being stable in the neutral state, the fully ionized Tl undergoes bound-state β decay to Pb with a half-life of days. The half-lives of neutral Ho and Pb are respectively 4570 years and years. In addition, it is estimated that β decay is energetically impossible for natural atoms but theoretically possible when fully ionized also for 193Ir, 194Au, 202Tl, 215At, 243Am, and 246Bk.
Another possibility is that a fully ionized atom undergoes greatly accelerated β decay, as observed for Re by Bosch et al., also at Darmstadt. Neutral Re does undergo β decay, with half-life years, but for fully ionized Re this is shortened to only 32.9 years. This is because Re is energetically allowed to undergo β decay to the first-excited state in Os, a process energetically disallowed for natural Re.
"Ordinary" 2β results in the emission of two electrons and two antineutrinos. If neutrinos are Majorana particles (i.e., they are their own antiparticles), then a decay known as neutrinoless double beta decay will occur. Most neutrino physicists believe that neutrinoless 2β has never been observed.
decay and electron capture
Non-conservation of parity
β− decay
β+ decay
Electron capture (K-capture/L-capture)
Nuclear transmutation
> (beta minus decay) (beta plus decay) (electron capture)
Competition of beta decay types
Stability of naturally occurring nuclides
Conservation rules for beta decay
Baryon number is conserved
Lepton number is conserved
Angular momentum
Energy release
Tritium β− decay being used in the KATRIN experimental search for sterile neutrinos.
> + Examples of beta decay energies
β− β− β+
εβ− β− β+
εε β− β−
β− decay
The value for this decay is
where is the mass of the nucleus of the atom, is the mass of the electron, and is the mass of the electron antineutrino. In other words, the total energy released is the mass energy of the initial nucleus, minus the mass energy of the final nucleus, electron, and antineutrino. The mass of the nucleus is related to the standard atomic mass by
That is, the total atomic mass is the mass of the nucleus, plus the mass of the electrons, minus the sum of all electron binding energies for the atom. This equation is rearranged to find , and is found similarly. Substituting these nuclear masses into the -value equation, while neglecting the nearly zero antineutrino mass and the difference in electron binding energies, which is very small for high- atoms, we have
This energy is carried away as kinetic energy by the electron and antineutrino.
β+ decay
giving
However, in this equation, the electron masses do not cancel, and we are left with
Electron capture
we have
which simplifies to
where is the binding energy of the captured electron.
Beta emission spectrum
Fermi function
Kurie plot
Helicity (polarization) of neutrinos, electrons and positrons emitted in beta decay
Types of beta decay transitions
Fermi transitions
Gamow–Teller transitions
Forbidden transitions
>
Rare decay modes
Bound-state β decay
"Note also, that the decay of bare 187Re is dominated by the nonunique transition to the first excited state of 187Os, since the decay to the ground state has a much smaller matrix element."
Double beta decay
See also
Bibliography
External links
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